Nature of the unpaired orbital of the disulphide anion as disclosed from 33S hyperfine coupling

Akira Naito, Kazuyuki Akasaka, Hiroyuki Hatano

  • 5 Citations

Abstract

33S-nuclear hyperfine structure has been analyzed in the ESR spectrum of the disulphide anion in γ-irradiated L-cystine dihydrochloride. The results have confirmed that the unpaired electron occupies an antibonding signa-type orbital consisting essentially of sulphur 3p orbitals. © 1975.

Original languageEnglish
Pages (from-to)247-249
Number of pages3
JournalChemical Physics Letters
Volume32
Issue number2
DOIs
StatePublished - 1975 Apr 15
Externally publishedYes

Fingerprint

Negative ions
Cystines
Paramagnetic resonance
Sulfur
Electrons

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Spectroscopy
  • Condensed Matter Physics
  • Atomic and Molecular Physics, and Optics
  • Surfaces and Interfaces

Cite this

Nature of the unpaired orbital of the disulphide anion as disclosed from 33S hyperfine coupling. / Naito, Akira; Akasaka, Kazuyuki; Hatano, Hiroyuki.

In: Chemical Physics Letters, Vol. 32, No. 2, 15.04.1975, p. 247-249.

Research output: Contribution to journalArticle

Naito, Akira; Akasaka, Kazuyuki; Hatano, Hiroyuki / Nature of the unpaired orbital of the disulphide anion as disclosed from 33S hyperfine coupling.

In: Chemical Physics Letters, Vol. 32, No. 2, 15.04.1975, p. 247-249.

Research output: Contribution to journalArticle

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