Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage

Ken Takano, Hiroyuki Tateno, Yoshimasa Matsumura, Atsushi Fukazawa, Tsuneo Kashiwagi, Koji Nakabayashi, Kensaku Nagasawa, Shigenori Mitsushima, Mahito Atobe

Abstract

The electrocatalytic hydrogenation of o-xylene in a proton-exchange membrane (PEM) reactor with various cathode catalysts was carried out as a study of a model reaction for hydrogen storage. o-Xylene introduced in a PEM reactor underwent electrocatalytic hydrogenation to provide cis-1,2-dimethylcyclohexane as the main stereoisomer with moderate to good current efficiencies. The reaction proceeded in accordance with the Langmuir-Hinshelwood mechanism.

Original languageEnglish
Pages (from-to)1437-1439
Number of pages3
JournalChemistry Letters
Volume45
Issue number12
DOIs
StatePublished - 2016

Fingerprint

Xylene
Hydrogenation
Ion exchange
Protons
Membranes
Xylenes
Hydrogen
Hydrogen storage
Stereoisomerism
Electrodes
Cathodes
Catalysts

Keywords

  • Electrocatalytic hydrogenation
  • Hydrogen storage
  • PEM reactor

ASJC Scopus subject areas

  • Chemistry(all)

Cite this

Takano, K., Tateno, H., Matsumura, Y., Fukazawa, A., Kashiwagi, T., Nakabayashi, K., ... Atobe, M. (2016). Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage. Chemistry Letters, 45(12), 1437-1439. DOI: 10.1246/cl.160766

Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage. / Takano, Ken; Tateno, Hiroyuki; Matsumura, Yoshimasa; Fukazawa, Atsushi; Kashiwagi, Tsuneo; Nakabayashi, Koji; Nagasawa, Kensaku; Mitsushima, Shigenori; Atobe, Mahito.

In: Chemistry Letters, Vol. 45, No. 12, 2016, p. 1437-1439.

Research output: Contribution to journalArticle

Takano, K, Tateno, H, Matsumura, Y, Fukazawa, A, Kashiwagi, T, Nakabayashi, K, Nagasawa, K, Mitsushima, S & Atobe, M 2016, 'Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage' Chemistry Letters, vol 45, no. 12, pp. 1437-1439. DOI: 10.1246/cl.160766
Takano K, Tateno H, Matsumura Y, Fukazawa A, Kashiwagi T, Nakabayashi K et al. Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage. Chemistry Letters. 2016;45(12):1437-1439. Available from, DOI: 10.1246/cl.160766

Takano, Ken; Tateno, Hiroyuki; Matsumura, Yoshimasa; Fukazawa, Atsushi; Kashiwagi, Tsuneo; Nakabayashi, Koji; Nagasawa, Kensaku; Mitsushima, Shigenori; Atobe, Mahito / Electrocatalytic hydrogenation of o-xylene in a PEM reactor as a study of a model reaction for hydrogen storage.

In: Chemistry Letters, Vol. 45, No. 12, 2016, p. 1437-1439.

Research output: Contribution to journalArticle

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