Associations of organic matter with minerals in Tagish Lake meteorite via high spatial resolution synchrotron-based FTIR microspectroscopy

Mehmet Yesiltas, Yoko Kebukawa

Abstract

We have investigated spatial and spectral associations between mineral species and organic matter in the Tagish Lake meteorite. Synchrotron-based infrared microspectroscopy allowed us to spatially locate specific organic and inorganic compounds within multiple Tagish Lake grains with high spatial resolution. Generated two-dimensional infrared maps present strong spatial association between aliphatic C-H and OH in phyllosilicates in Tagish Lake grains. These observations indicate possible roles of phyllosilicates for the formation, evolution, and preservation of organic matter. Infared spectra of all studied Tagish Lake grains show a strong carbonate band, which also shows a weak but positive correlation with organic matter in some grains. However, intergrain correlation was not observed between carbonates and organics, which is likely due to the difference of carbonate occurrence, e.g., presence of larger grains or intergrowth of carbonates on phyllosilicates. Possible scenarios further explaining the observed associations of organics with phyllosilicates and carbonates are presented.

Original languageEnglish
Pages (from-to)584-595
Number of pages12
JournalMeteoritics and Planetary Science
Volume51
Issue number3
DOIs
StatePublished - 2016 Mar 1

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carbonate
lake
phyllosilicate
organic matter
meteorite
spatial resolution
mineral
inorganic compound
organic compound

ASJC Scopus subject areas

  • Geophysics
  • Space and Planetary Science

Cite this

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author = "Mehmet Yesiltas and Yoko Kebukawa",
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journal = "Meteoritics and Planetary Science",
issn = "1086-9379",
publisher = "The University of Arkansas Press",
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N2 - We have investigated spatial and spectral associations between mineral species and organic matter in the Tagish Lake meteorite. Synchrotron-based infrared microspectroscopy allowed us to spatially locate specific organic and inorganic compounds within multiple Tagish Lake grains with high spatial resolution. Generated two-dimensional infrared maps present strong spatial association between aliphatic C-H and OH in phyllosilicates in Tagish Lake grains. These observations indicate possible roles of phyllosilicates for the formation, evolution, and preservation of organic matter. Infared spectra of all studied Tagish Lake grains show a strong carbonate band, which also shows a weak but positive correlation with organic matter in some grains. However, intergrain correlation was not observed between carbonates and organics, which is likely due to the difference of carbonate occurrence, e.g., presence of larger grains or intergrowth of carbonates on phyllosilicates. Possible scenarios further explaining the observed associations of organics with phyllosilicates and carbonates are presented.

AB - We have investigated spatial and spectral associations between mineral species and organic matter in the Tagish Lake meteorite. Synchrotron-based infrared microspectroscopy allowed us to spatially locate specific organic and inorganic compounds within multiple Tagish Lake grains with high spatial resolution. Generated two-dimensional infrared maps present strong spatial association between aliphatic C-H and OH in phyllosilicates in Tagish Lake grains. These observations indicate possible roles of phyllosilicates for the formation, evolution, and preservation of organic matter. Infared spectra of all studied Tagish Lake grains show a strong carbonate band, which also shows a weak but positive correlation with organic matter in some grains. However, intergrain correlation was not observed between carbonates and organics, which is likely due to the difference of carbonate occurrence, e.g., presence of larger grains or intergrowth of carbonates on phyllosilicates. Possible scenarios further explaining the observed associations of organics with phyllosilicates and carbonates are presented.

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